Search results for "Phosphate glass"
showing 9 items of 9 documents
New low-temperature phosphate glasses as a host for Europium Ions
2021
Abstract Artificial lightining, especially that of light emitting diodes, and telecommunications are penetrating every part of human lives daily. Different compositions phosphate glasses were suggested as a suitable host material for Eu3+ ions. Here rare earth metal ions act as luminescent centers also perturbing the bond order of phosphate glass network comprised of (PO4)3−, [−(O)PO3]2−, [−(O)2PO2]−, [−(O)3PO] structural units, which is indicated by Raman spectroscopy, confirming successful integration of aforementioned ions into the glass material. Glasses doped with Eu3+ ions show their typical photoluminescence spectra in low symmetry environment, consisting of the highest intensity 5D0…
Effect of sodium to barium substitution on the space charge implementation in thermally poled glasses for nonlinear optical applications
2009
Thermally poled niobium borophosphate glasses in the system 0.55(0.95-y) NaPO{sub 3}+y/2 Ba(PO{sub 3}){sub 2}+0.05Na{sub 2}B{sub 4}O{sub 7})+0.45Nb{sub 2}O{sub 5} were investigated for second order optical nonlinear (SON) properties. Bulk glasses were studied by Raman spectroscopy, thermal analysis, optical and dielectric measurements. The sodium to barium substitution does not lead to significant changes in optical properties, crystallization of glasses and coordination environment of polarizable niobium atoms. However, the ionic conductivity decreases drastically with the increase of barium concentration. Secondary ion mass spectroscopy has been used to determine the element distribution …
Luminescence of phosphorus containing oxide materials: Crystalline SiO2‐P and 3P2O5⋅7SiO2; CaO⋅P2O5; SrO⋅P2O5 glasses
2014
Luminescence of phosphate glasses such as CaO⋅P2O5 and SrO⋅P2O5 is compared with that of phosphorus doped crystalline α-quartz and phosphosilicate glass with content 3P2O5⋅7SiO2. Water & OH groups are found by IR spectra in these materials. The spectrum of luminescence contains many bands in the range 1.5 - 5.5 eV. The luminescence bands in UV range at 4.5-5 eV are similar in those materials. Decay duration in exponential approximation manifests a time constant about 37 ns. Also a component in μs range was detected. PL band of μs component is shifted to low energy with respect to that of ∼37 ns component. This shift is about 0.6 eV. It is explained as singlet-triplet splitting of excited st…
Raman spectroscopic study of some lead phosphate glasses with tungsten ions
2006
Abstract The structure of x WO 3 · (100 − x )[2P 2 O 5 · PbO] glass system with 0 ⩽ x ⩽ 50 mol% was investigated by Raman spectroscopy. The characteristic bands of these glasses due to the stretching and bending vibrations were identified and analyzed by the increasing of WO 3 content. This fact allowed us to identify the specific structural units which appear in these glasses and thus to point out the network modifier role of tungsten oxide for low concentrations and its former role at high concentrations.
Core-clad phosphate glass fibers for biosensing
2019
Recently, a phosphate glass with composition 20 CaO-20 SrO-10 Na2O-50 P2O5 (mol%) was found to have good potential as a biomaterial and to possess thermal properties suitable for fiber drawing. This study opened the path towards the development of fully bioresorbable fibers promising for biosensing. In the past, this phosphate glass with CeO2 was found to increase the refractive index and the glass stability. Therefore, a new SrO-containing glass was prepared with 1 mol% of CeO2 and core fibers were drawn from it. A core-clad fiber was also processed, where the core was a Ce-doped glass and the clad undoped, to allow for total internal reflection. The mechanical properties of the core and c…
Low temperature afterglow from SrAl 2 O 4 : Eu, Dy, B containing glass
2020
V.V. acknowledges the financial support of ERDF PostDoc project No. 1.1.1.2/VIAA/3/19/440 (University of Latvia Institute of Solid State Physics, Latvia) and LP the Academy of Finland (Flagship Programme, Photonics Research and Innovation PREIN 320165 and Academy Project -326418) for the financial support. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01- 2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART 2 .
50 mJ/30 ns FTIR Q-switched diode-pumped Er:Yb:glass 1.54 μm laser
2001
Abstract 50 mJ Q-switched output at 30 ns pulse duration was demonstrated with a transversely diode-pumped bulk Er 3+ :Yb 3+ :glass 1.54 μm laser system of uncomplicated and compact design, using a piezoelectrically driven FTIR shutter. In long-pulse operation, 360 mJ output was obtained for 2.65 J incident optical pump energy. Maximum optical slope efficiencies of 20.5% and 5.4% were measured in long-pulse and Q-switched operation, respectively. Optimum Q-switch timing was studied taking into account the Yb 3+ →Er 3+ energy transfer process and was correlated with free-running delay parameters.
Low Temperature Afterglow from SrAl <sub>2</sub>O <sub>4</sub>: EU, Dy, B Containing Glass
2020
SrAl2O4: Eu, Dy, B particles were added in a phosphate glass (90NaPO3-10NaF (in mol%)) using the direct doping method. For the first time, the composition of the particles prior to and after embedding them in the glass was analysed using EPMA analysis. Boron was found to be incorporated in already distorted surroundings creating new trapping centers in the particles which are thought to be favourable for the tunnelling process and so for the afterglow at 10K. Despite the partial decomposition of the particles, the glass exhibit afterglow at low temperature confirming to be promising materials for low temperature applications.
Surface versus bulk composition of a phosphate glass
1994
Transmission and conversion electron Mossbauer spectroscopy as well as photoelectron spectroscopy were applied to study alterations of the surface layer of an iron containing industrial phosphate glass as compared with its bulk. In the surface layer, after polishing and exposure to ambient atmosphere, Fe 2+ is partially oxidized to Fe 3+ . This oxidation, however, does not increase the O/P ratio in this layer, because it goes along with a strong leaching of network modifiers. This leaching leads to a net decrease of the O/P ratio because it overcompensates the relative oxygen increase by Fe 2+ oxidation and by uptake of water